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Producción de hidrógeno por reformado de etanol usando el catalizador bimetálico Rh-Pt/La2O3

dc.contributor.advisorCobo Ángel, Martha Isabel
dc.contributor.authorPieruccini Ramírez, Diana Carolina
dc.date.accessioned2013-12-17T20:01:16Z
dc.date.available2013-12-17T20:01:16Z
dc.date.issued2013-12-17
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dc.identifier.urihttp://hdl.handle.net/10818/9492
dc.description135 páginas
dc.description.abstractEn esta tesis se llevó a cabo el estudio de la actividad catalítica del catalizador RhPt/La2O3 en la reacción de reformado con vapor de etanol (RVE) para la producción de H2. El catalizador se preparó por el método de impregnación húmeda incipiente con cargas de metales Rh y Pt de 6% y 2% respectivamente. El estudio se realizó con el fin de contribuir al desarrollo de un catalizador activo para su posible aplicación en sistemas catalíticos que puedan ser insertados a bordo de vehículos eléctricos y así producir y consumir H2 mediante una serie de etapas catalíticas integradas. Para tal efecto el catalizador fue sometido a una serie de experimentos que permitieron evaluar el impacto de diferentes variables operación sobre la distribución de productos. En este sentido, los resultados experimentales y termodinámicos mostraron un comportamiento similar al incrementar la fracción mol de agua en el alimento, favoreciendo el rendimiento a H2 y disminuyendo la producción de CO y CH4, gracias al aumento en la velocidad de las reacciones de reformado con vapor de etanol (RVE) y de desplazamiento del gas de agua (RDGA). Por otro lado, el incremento de la temperatura favoreció la producción de CO e H2 y disminuyó la producción de CO2 lo cual indica que el aumento en la producción de H2 está relacionado con la alta favorabilidad del RVE a mayor temperatura, mientras que el aumento de CO y la disminución de CO2 muestran la desfavorabilidad de la RDGA con la temperatura.es_CO
dc.language.isospaes_CO
dc.publisherUniversidad de La Sabana
dc.sourceUniversidad de La Sabana
dc.sourceIntellectum Repositorio Universidad de La Sabana
dc.subjectCatalizadores metálicos
dc.subjectHidrógeno
dc.subjectHidrógeno como combustible -- Catalizadores
dc.titleProducción de hidrógeno por reformado de etanol usando el catalizador bimetálico Rh-Pt/La2O3es_CO
dc.typemasterThesis
dc.publisher.programMaestría en Diseño y Gestión de Procesos
dc.publisher.departmentFacultad de Ingeniería
dc.identifier.localTE06263
dc.type.localTesis de maestría
dc.type.hasVersionpublishedVersion
dc.rights.accessRightsopenAccess
dc.creator.degreeMagíster en Diseño y Gestión de Procesos


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